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The Influence of Mechanical Milling on the Structure and Magnetic Properties of Sm-Fe-N Powder Produced by the Reduction-Diffusion Process

Journal of Magnetics, Volume 16, Number 2, 30 Jun 2011, Pages 104-107
Jung-Goo Lee * (Functional Materials Division, Korea Institute of materials Science), Seok-Won Kang (Functional Materials Division, Korea Institute of materials Science), Ping-Zhan Si (College of Materials Science & Engineering, China Jiliang University), Chul-Jin Choi (Functional Materials Division, Korea Institute of materials Science)
Abstract

In the present study, we systematically investigated the effect of mechanical milling on the magnetic properties of Sm2Fe17Nx powders produced by the reduction-diffusion process. The Sm-Fe powders obtained by the reduction-diffusion process were composed of an Sm2Fe17 single phase. After nitrogenation, the coercivity and saturation magnetization of the powders were 0.48 kOe and 13.32 kG, respectively. The particle size largely decreased down to less than 2 μm in diameter after ball milling for 30 hours. However, there is no evidence that the Sm2Fe17Nx was decomposed to Sm-N and α-Fe even after ball milling for 30 hours. The coercivity was significantly improved up to 8.82 kOe after milling for 60 hours. However, the magnetization decreased linearly with the ball milling time.

 

Keywords: reduction-diffusion; Sm-Fe-N; magnetic powder; ball milling
DOI: 10.4283/JMAG.2011.16.2.104
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