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Coercivity of Near Single Domain Size Nd2Fe14B-type Particles

Journal of Magnetics, Volume 17, Number 3, 30 Sep 2012, Pages 185-189
H. W. Kwon * (Pukyong National University), J. H. Yu (Korea Institute of Materials Science)
Abstract

The coercivity of near single domain size Nd2Fe14B-type particles prepared by ball milling of HDDR-treated Nd12.5Fe80.6B6.4Ga0.3Nb0.2 alloy was investigated. The feasibility of a surface nitrogenation for improving the coercivity stability of the fine Nd2Fe14B-type particles was also studied. The near single domain size Nd2Fe14B-type  particles had a high coercivity of over 9 kOe. However, the coercivity radically deteriorated as the temperature increased in air (< 2 kOe at 200 oC). This coercivity reduction was attributed to the soft magnetic phases, α-Fe and Fe3B, which formed on the surface of the fine particle due to oxidation. Surface nitrogenation of the fine particles significantly improved the stability of their coercivity. The improvement in coercivity stability was attributed to the formation of a thin nitrogenated layer on the surface of the fine Nd2Fe14B-type particles, which enhanced the anisotropy field and gave improved resistance to oxidation (dissociation).

 

Keywords: Nd2Fe14B; single domain size particle; oxidation; coercivity; nitrogenation
DOI: http://dx.doi.org/10.4283/JMAG.2012.17.3.185
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