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Structural and Magnetic Properties of Dilute Spinel Ferrites: Neutron Diffractometry and Magnetometry Investigations

Journal of Magnetics, Volume 16, Number 2, 30 Jun 2011, Pages 134-139
H. Mamiya * (National Institute for Materials Science), N. Terada (National Institute for Materials Science), H. Kitazawa (National Institute for Materials Science), A. Hoshikawa (Ibaraki University), T. Ishigaki (Ibaraki University)
Abstract

Magnetic properties of highly zinc-substituted manganese ferrites are discussed on the basis of cation
distribution. High throughput neutron powder diffractometry indicates that the prepared samples possess a
nearly normal spinel structure, where the substitution of nonmagnetic zinc ions mainly causes the dilution of magnetic ions in the A-sublattice and consequently affects bond-randomness in the B-sublattice. On the other hand, the estimated occupancy of manganese ions in the B site indicates that random anisotropy effects due to local Jahn-Teller distortions gradually weaken with the substitution. Bulk magnetometry indicates that the substitution smears the transition from a paramagnetic phase to a soft-magnetic phase. Furthermore, at lower temperatures, such a soft-magnetic phase is destabilized and a magnetic glassy state appears. These features of the magnetic properties of dilute spinel ferrites are discussed from the viewpoint of the above-mentioned various types of disorders.

 

Keywords: oxide spinel; TOF neutron diffraction; diluted ferrimagnet; smeared phase transition; reentrant spin-glass
DOI: 10.4283/JMAG.2011.16.2.134
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