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Home > Issues > Volume 6 (2001) > No.2(pp.43-76)

Structure and Magnetic Properties of Mechanically Alloyed Sm(Fe,Ti)7 Compounds and Their Nitrides

Journal of Magnetics, Volume 6, Number 2, 30 Jun 2001, Pages 57-60
H. T. Kim(Department of Metallurgical Engineering, Chungnam National University)
Abstract
Mechanically alloyed TbCu7-type Sm12.5Fe87.5-xTix (x=0, 2.5, 5, 7.5),and their nitrides have been studied systematically by X-ray diffraction, A.C. initial susceptibility, and pulsed magnetization measurement. In this series, the volume expansion by nitriding is 5.6%~7.3%, and the increment of the Curie temperature is in the range of 210 ℃~350 ℃. With increasing Ti content, the remanence decreases linearly due to the substitution of non-magnetic Ti, and the coercivity decreases rapidly from 34.6 kA/cm (43.5 kOe) for x=0 to 14.3 kA/cm (18 kOe) for x=7.5. In the Sm12.5Fe87.5-xTixNy series, the best magnetic properties were obtained from Sm12.5Fe87.5Ny (x=0) with iHc=34.6 kA/cm (43.5 kOe), Br=0.75 T, and (BH)max=113.8 kJ/m3 (10.9 MGOe).
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