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Effect of Various Composition Ratios on the Exchange Spring Effect in SrFe12O19/CoFe2O4 Nanocomposite Magnets

Journal of Magnetics, Volume 28, Number 3, 30 Sep 2023, Pages 251-257
Novrita Idayanti (National Research and Innovation Agency), Dedi (National Research and Innovation Agency), Dadang Mulyadi (National Research and Innovation Agency), Tony Kristiantoro (National Research and Innovation Agency), Nanang Sudrajat (National Research and Innovation Agency), Gandi Sugandi (National Research and Innovation Agency), Azwar Manaf * (Universitas Indonesia)
Abstract
This study aims to examine the effect of various composition ratios on the exchange spring effect of strontium
ferrite (SrFe12O19)/cobalt ferrite (CoFe2O4) nanocomposite magnets. Nanoparticles of hexagonal hard phase
SrFe12O19 and spinel soft phase CoFe2O4 were each prepared through mechanical alloying and high-power
ultrasonic irradiation processes. Furthermore, the constituent of the hard-soft particles was weighed based on
its ratios and the mixture was homogenized under a sonicator-type Qsonica at a frequency of 20 kHz for an
hour. The bulk composite samples were obtained in cylindrical pellets form through compaction of mixture
powders at 5000 kg/cm2, followed by sintering at 1200 °C. The exchange spring effect enhanced the magnetic
properties, surpassing the normal limit for non-interacting magnetic particles due to enhanced grain interactions.
The results showed that the degree of property enhancement depended on the various composition ratios
and microstructure of the composite magnets. The magnetization of saturation (Ms) of the samples increased
compared to a single SrFe12O19. Furthermore, the highest coercivity (Hc) and product energy maximum
(BH)max values were observed in the sample which had mass ratios of SHF:COF of 85:15 with coded S80C20.
The occurrence of exchange spring effects was observed in material characterized by a microstructure consisting
of a hard-magnetic phase with elevated magnetocrystalline anisotropy and saturation magnetization values,
along with a soft magnetic phase exhibiting high saturation magnetization value.
Keywords: exchange spring magnet; nanocomposite; SrFe12O19; CoFe2O4
DOI: https://doi.org/10.4283/JMAG.2023.28.3.251
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