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Magnetic and Magnetocaloric Properties of Pr2Fe17-xCux Intermetallic Compounds

Journal of Magnetics, Volume 26, Number 3, 30 Sep 2021, Pages 332-340
N. E. Cengiz (Inonu University), M. Pektas (Inonu University), V. S. Kolat (Inonu University), T. Izgi (Inonu University), H. Gencer (Inonu University), N. Bayri (Inonu University), S. Atalay * (Inonu University)
Abstract
In this study, Cu-doped intermetallic compounds with the chemical composition of Pr2Fe17-xCux (x = 0, 0.1, 0.2)
were prepared by the arc-melting process. SEM analysis revealed that the samples consist of irregularly shaped
and strongly connected micron-scale particles range from 0.5 μm to 4 μm. EDX analysis showed that all the
samples consist of a single phase. The magnetic measurements revealed that all the samples exhibit a ferromagnetic
to the paramagnetic phase transition. The Curie temperature was determined to increase linearly with
increasing Cu substitution from 286 K for x = 0 to 303 K for x = 0.2. The maximum value of magnetic entropy
change |ΔSm| was estimated from isothermal magnetization curves and it decreases with increasing Cu content
from 5.63 J/kg·K for x = 0 to 4.21 J/kg·K for x = 0.2 at 5 T magnetic field change. At the same magnetic field
change, the relative cooling power values range from 404.8 J/Kg for x = 0 to 248.3 J/Kg for x = 0.2. Arrott plots
and Landau analyses revealed that all the samples show second-order magnetic phase transition.
Keywords: 2:17 type intermetallic compounds; Cu substitution; magnetic entropy change; magnetocaloric effect
DOI: https://doi.org/10.4283/JMAG.2021.26.3.332
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