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Phase Distribution and Coercivity Enhancement in (MM,Nd)-Fe-B Magnets with Dual-main-phase

Journal of Magnetics, Volume 26, Number 2, 30 Jun 2021, Pages 194-198
Dong-wei Duan (Inner Mongolia University), Lei Wei (Inner Mongolia University), Zhu-bai Li * (Inner Mongolia University), Qian Zhao (Inner Mongolia University), Yong-feng Li (Inner Mongolia University)
Abstract
The mischmetal-based sintered magnets were prepared by mixing MM8.8Nd3.4Fe81.8B6 (MM denotes mischmetal)
with Nd15Fe79B6 alloys. The magnet consist of two main phases i.e., (La,Ce)-rich main phase and Ndrich
main phase. For the mass ratio of 8:2 of MM8.8Nd3.4Fe81.8B6 and Nd15Fe79B6, many grains of La-Ce-rich
main phase are interconnected and the effect of enhancing the coercivity is weak in the sintered magnets. While
for the mass ratio of 6:4 most grains of (La,Ce)-rich main phase are nearly separated and covered by the Ndrich
main phase and intergranular phase, and the coercivity increases significantly to 7.70 kOe. Compared with
(MM0.3Nd0.7)30.3FebalB0.96Cu0.1Al0.11 magnets prepared by the conventional method, the coercivity doesn’t
decrease in the sintered composite magnets of MM8.8Nd3.4Fe81.8B6/Nd15Fe79B6 though the MM content of 40
wt.% is higher. The optimization of Nd-rich-main-phase distribution as well as Nd substitution for La-Ce
should be responsible for the significant increase of coercivity.
Keywords: mischmetal-based magnets; composite magnets; phase distribution; substitution; coercivity
DOI: https://doi.org/10.4283/JMAG.2021.26.2.194
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