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Enhancing the Magnetic and Magneto-optical Properties of Praseodymium-substituted Bi-YIG Thin Film on Glass Substrate Prepared by Metal-organic Decomposition

Journal of Magnetics, Volume 26, Number 1, 31 Mar 2021, Pages 14-18
Viet Dongquoc (Department of Materials Science and Engineering, Chungnam National University), Trinh Nguyen Thi (Department of Materials Science and Engineering, Chungnam National University), Phuoc Cao Van (Department of Materials Science and Engineering, Chungnam National University), Duc Duong Viet (Department of Materials Science and Engineering, Chungnam National University), Ha-Young Ahn (Department of Materials Science and Engineering, Chungnam National University), Eui-Tae Kim (Department of Materials Science and Engineering, Chungnam National University), Seung-Young Park * (Center for Scientific Instrumentation, Korea Basic Science Institute), Jong-Ryul Jeong * (Department of Materials Science and Engineering, Chungnam National University)
Abstract
Praseodymium (Pr)- and bismuth (Bi)-substituted yttrium (Y) iron (Fe) garnet (PrxY2-xBi1Fe5O12 where x =
0.25, 0.5, 1, and 2) thin films were prepared on glass substrate using a metal-organic decomposition (MOD)
method. Their magneto-optical properties were studied as a function of Pr concentration. Praseodymium has
two functions in PrxY2-xBi1Fe5O12 thin films, i.e., it (i) improves spin-orbit interaction strength and (ii) increases
magnetic properties; both are expected to strongly enhance the Faraday rotation (FR) angle of the thin film.
Our study demonstrated that the Pr1Y1Bi1Fe5O12 thin-film displayed the highest FR angle, of –13 °/μm, which
is 1.6-times higher than that of the PrxY2-xBi1Fe5O12 thin film without Pr dopant. The Pr1Bi1Y1Fe5O12 thin film
fabricated on a glass substrate by the MOD method displayed excellent MO performance and is a potential
candidate for application in optical devices.
Keywords: Bi-YIG thin films; Faraday rotation; magneto-optical properties; metal-organic decomposition; polyvinylpyrrolidone
DOI: https://doi.org/10.4283/JMAG.2021.26.1.014
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