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Effects of Scandium Doping on Structural and Magnetic Properties of Cobalt Ferrite Thin Films

Journal of Magnetics, Volume 25, Number 4, 31 Nov 2020, Pages 453-457
Kwang Joo Kim (Department of Physics, Konkuk University), Jongho Park (Department of Physics, Konkuk University), Jae Yun Park * (Department of Materials Science and Engineering, Incheon National University)
Abstract
Structural and magnetic properties of Sc-substituted cobalt ferrites were studied by X-ray diffraction, Raman
spectroscopy, X-ray photoelectron spectroscopy, and vibrating-sample magnetometry. The  ScxCoFe2-xO4 (x ≤
0.3) specimens prepared as thin films by a sol-gel deposition method were polycrystalline having cubic spinel
structure with a small increase in the lattice constant compared to CoFe2O4. The Raman spectral analyses suggested
that the Sc-doped specimens have higher tetrahedral Co2+ population than that of pristine CoFe2O4. The
magnetic hysteresis curves of the ScxCoFe2-xO4 specimens indicated that the saturation and remanent magnetization
decrease proportionally with the increase of Sc composition (x). The decrease in the ferrimagnetic
parameters is understandable in terms of the octahedral substitution of non-magnetic Sc3+ ions. However, the
octahedral Sc3+ ions caused an increase of the coercivity.
Keywords: ferrite, scandium, thin film, magnetic properties, structural properties
DOI: https://doi.org/10.4283/JMAG.2020.25.4.453
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