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Crystal Structures and Magnetic Properties of Silica-Encapsulated CoZnFe2O4 Magnetic Nanoparticles
Journal of Magnetics, Volume 24, Number 1, 31 Mar 2019, Pages 149-154
Abstract
Zinc-doped cobalt ferrite magnetic nanoparticles (CoZnFe2O4) with silica encapsulation have been successfully synthesized by using coprecipitation method. The concentration of silica was varied by 0 %, 5 %, 10 %, 15 %, 20 %, 30 % and 50 % of weight. The XRD spectra show that all samples have the character of the main spinel diffraction peaks (2θ) attributed to the (220), (311), (400), (422), and (511) planes. The FTIR analysis shows that the intrinsic stretching vibrations of metal-oxygen at the frequency range of 393 cm−1 - 401 cm−1 and 470 cm−1 - 563 cm−1 were found at octahedral and tetrahedral sublattices, respectively. The unencapsulated CoZnFe2O4 nanoparticle has coercivity (Hc) and maximum magnetization (M) of 251 Oe and 29.0 emu/gram, respectively. The coercivity value of the encapsulated nanoparticles increases up to 853 Oe with the increase of silica concentration, while the maximum magnetization decreases to 24.2 emu/gram.
Keywords: CoZnFe2O4 magnetic nanoparticles; coprecipitation; encapsulation; silica
DOI: https://doi.org/10.4283/JMAG.2019.24.1.149
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