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Effect of Gd Substitution on the Structural, Magnetic, and Magnetocaloric Properties of Fe68Tb5B23Nb4 Metallic Glass

Journal of Magnetics, Volume 24, Number 1, 31 Mar 2019, Pages 43-48
Ersin Civan (National Defence University, Air Non-Commissioned Officer (NCO) Higher Vocational School), Kagan Sarlar (Physics Department, Faculty of Arts and Sciences, Uludag University), Ilker Kucuk * (Physics Department, Faculty of Arts and Sciences, Uludag University)
Abstract
The effects of adding Gd on the Curie temperature (TC), glass-forming ability (GFA), and magnetocaloric effect (MCE) were studied in Fe68-xGdxTb5B23Nb4 (x = 0, 2, and 6) glassy alloys prepared by suction casting. It was shown that when Gd content was exchanged with Fe partially for x = 2, GFA was increased, whereas for x = 6, adding Gd content has reduced the GFA and amorphous structure could not be obtained. Critical diameter was found to be 3 mm for Fe66Gd2Tb5B23Nb4 bulk metallic glass (BMG). By exchanging Gd with Fe partially, TC could effectively be tuned in a quite broad temperature interval from 487 K (x = 0) to 380 K (x = 6) for which amorphous structure could not be obtained. Maximum magnetic entropy change (−ΔSM)max values were found to be 1.16, 0.84 Jkg−1K−1, and 0.54 Jkg−1K−1 as well as, refrigeration capacity (RC) values were obtained as 116 J/kg, 84.84 J/kg, and 40.50 J/kg under a low field change of 2 T for x = 0, 2, and 6, respectively. Although TC was shifted to lower temperatures by exchanging Fe with Gd partially, (−ΔSM)max decreased almost half of the base alloy and RC decreased approximately 1/3 of the base alloy.
 
Keywords: Metallic glasses; Gd; magnetocaloric effect; magnetic entropy change
DOI: https://doi.org/10.4283/JMAG.2019.24.1.043
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