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Home > Issues > Volume 10 (2005) > No.3(pp.77-132)

Optical Properties of Two Different Metallic NaxCoO2: x =0.35 and 0.75

Journal of Magnetics, Volume 10, Number 3, 30 Sep 2005, Pages 128-132
J. Hwang* (Department of Physics and Astronomy, McMaster University), J. Yang(The Canadian Institute of Advanced Research), T. Timusk(Department of Physics and Astronomy, McMaster University), F.C Chou(Center for Materials Science and Engineering, MIT)
Abstract
We report optical ab-plane properties of the layered sodium cobaltate, NaxCoO2 for x = 0.35 and 0.75. Two samples show metallic behaviors according to dc resistivity transport. Overall temperature dependent optical conductivities of both samples are very similar to those of the high temperature superconducting underdoped cuprates. We found that the optical scattering rate of x = 0.75 sample, which is in a Curie-Weiss metallic phase, varies linearly (non-Fermi liquid) with frequency and temperature while that of x = 0.35 sample, which is in a paramagnetic metallic phase, varies quadratically (Fermi liquid) with frequency and temperature. Both x = 0.35 and 0.75 samples have an onset of scattering around 600 cm-1 which can be attributed to the interaction of charge carriers with a bosonic collective mode in a system.
Keywords: Sodium cobaltate; Optical conductivity; Optical scattering rate; Bosonic collective mode
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