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Magnetic and Magnetocaloric Properties of (Gd1-xCex)Al2 (x = 0, 0.25, 0.5, 0.75) Compounds |
Journal of Magnetics, Volume 16, Number 4, 31 Dec 2011, Pages 337-341 |
H. Gencer * (Physics Department, Science and Arts Faculty, Inonu University), T. Izgi, (Physics Department, Science and Arts Faculty, Inonu University), V. S. Kolat (Physics Department, Science and Arts Faculty, Inonu University), A. O. Kaya (Physics Department, Science and Arts Faculty, Inonu University), S. Atalay (Physics Department, Science and Arts Faculty, Inonu University) |
Abstract |
The magnetic and magnetocaloric properties of Gd1-xCexAl2 (x = 0, 0.25, 0.5, 0.75) intermetallic compounds alloys have been investigated in detail for the first time. XRD patterns indicated that all the samples were crystallized in a single phase with MgCu2-type structure (Laves phase). Ce substitution for Gd increased the lattice parameters and decreased the Curie temperature from 163 K for x = 0 to 37 K for x = 0.75. A maximum entropy change of 3.82 J/kg K was observed when a 2 T magnetic field was applied to the x = 0 sample. This entropy change decreased with increasing Ce content to 2.04 J/kg K for the x = 0.75 sample.
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Keywords: magnetic properties; magnetocaloric effect; intermetallic compounds; laves phase |
DOI: http://dx.doi.org/10.4283/JMAG.2011.16.4.337 |
Full Text: PDF |
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