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Synthesis and Magnetic Properties of Zn, Co and Ni Substituted Manganese Ferrite Powders by Sol-gel Method
Journal of Magnetics, Volume 15, Number 4, 31 Dec 2010, Pages 159-164
Woo Hyun Kwon (Department of Applied Physics, Konkuk University), Jeoung Yun Kang (Department of Applied Physics, Konkuk University), Jae-Gwang Lee (Department of Applied Physics, Konkuk University), Seung Wha Lee (Department of Applied Physics, Konkuk University), Kwang Pyo Chae * (Department of Applied Physics, Konkuk University)
Abstract

The Zn, Co and Ni substituted manganese ferrite powders, Mn1-x(Zn, Co, Ni)xFe2O4, were fabricated by the solgel method, and their crystallographic and magnetic properties were studied. The Zn substituted manganese ferrite, Zn0.2Mn0.8Fe2O4, had a single spinel structure above 400 oC, and the size of the particles of the ferrite powder increased when the annealing temperature was increased. Above 500 oC, all the Mn1-x(Zn, Co, Ni)xFe2O4 ferrite had a single spinel structure and the lattice constants decreased with an increasing substitution of Zn, Co, and Ni in Mn1-x(Zn, Co, Ni)xFe2O4. The Mössbauer spectra of Mn1-x ZnxFe2O4(0.0≤x≤0.4) could be fitted as the superposition of two Zeeman sextets due to the tetrahedral and octahedral sites of the Fe3+ ions. For x = 0.6 and 0.8 they showed two Zeeman sextets and a single quadrupole doublet, which indicated they were ferrimagnetic and paramagnetic. And for x = 1.0 spectrum showed a doublet due to a paramagnetic phase. For the Co and Ni substituted manganese ferrite powders, all the Mössbauer spectra could be fitted as the superposition of two Zeeman sextets due to the tetrahedral and octahedral sites of the Fe3+ ions. The variation of the Mössbauer parameters are also discussed with substituted Zn, Co and Ni ions. The increment of the saturation magnetization up to x = 0.6 in Mn1-x CoxFe2O4could be qualitatively explained using the site distribution and the spin magnetic moment of substituted ions. The saturation magnetization and coercivity of the Mn1-x(Zn, Co, Ni)xFe2O (x = 0.4) ferrite powders were also compared with pure MnFe2O4.


 

Keywords: manganese ferrite; sol-gel method; mössbauer spectroscopy; coercivity; saturation magnetization
DOI: 10.4283/JMAG.2010.15.4.159
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