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Effect of Copper Substitution on Structural and Magnetic Properties of NiZn Ferrite Nanopowders |
Journal of Magnetics, Volume 18, Number 4, 31 Dec 2013, Pages 391-394 |
Mohammad Niyaifar * (Department of Physics, Science and Research Branch, Islamic Azad University), Hoda Shalilian (Department of Physics, Science and Research Branch, Islamic Azad University), Ahmad Hasanpour (Department of Physics, Science and Research Branch, Islamic Azad University), Hory Mohammadpour (Department of Physics, Science and Research Branch, Islamic Azad University) |
Abstract |
In this study, nickel-zinc ferrite nanoparticles, with the chemical formula of Ni0.3Zn0.7-xCuxFe2O4 (where x = 0.1-0.6 by step 0.1), were fabricated by the sol-gel method. The effect of copper substitution on the phase formation and crystal structure of the sample was investigated by X-ray diffraction (XRD), thermo-gravimetry (TG), differential thermal analysis (DTA), Fourier transform infrared spectrometry (FT-IR), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The XRD result shows that due to the reduction of Zn content,the crystallite size of the sample increased. The results of the vibration sample magnetometer (VSM) exhibit an increase in saturation magnetization value (Ms) for samples with x ≤ 0.3 and a linear decrease for samples with x > 0.3. The variation of saturation magnetization and coercivity of the samples were then studied.
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Keywords: Cu substituted nickel-zinc ferrite; sol-gel; magnetic properties |
DOI: http://dx.doi.org/10.4283/JMAG.2013.18.4.391 |
Full Text: PDF |
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