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Structural and Magnetic Properties of Ni0.6Zn0.4Fe2O4 Ferrite Prepared by Solid State Reaction and Sol-gel
Journal of Magnetics, Volume 19, Number 1, 31 Mar 2014, Pages 64-67
Yoon Mi Kwon (Department of Physics and Oxide Research Center, Hankuk University of Foreign Studies), Min-Young Lee (Department of Physics and Oxide Research Center, Hankuk University of Foreign Studies), Millaty Mustaqima (Department of Physics and Oxide Research Center, Hankuk University of Foreign Studies), Chunli Liu (Department of Physics and Oxide Research Center, Hankuk University of Foreign Studies), Bo Wha Lee * (Department of Physics and Oxide Research Center, Hankuk University of Foreign Studies)
Abstract

Ni0.6Zn0.4Fe2O4 prepared using solid state reaction and sol-gel methods were compared for their structural and magnetic properties. Due to the much higher annealing temperature used in solid state reaction, the crystalline size was much larger than that of the nanoparticles prepared by sol-gel. The saturation magnetization of sol-gel nanoparticles was higher, and the coercivity was about 2 times larger, compared to the solid state reaction sample. By analyzing the integration intensity of x-ray diffraction peaks (220) and (222), we proposed that the difference in the saturation magnetization might be due to the inversion of cation distribution caused by the different preparation techniques used.


 

Keywords: NiZn ferrite; nanoparticles; magnetization; coercivity; cation distribution
DOI: http://dx.doi.org/10.4283/JMAG.2014.19.1.064
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