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Coercivity of Hot-pressed Compacts of Nd-Fe-B-type HDDR-treated Powder
Journal of Magnetics, Volume 19, Number 2, 30 Jun 2014, Pages 106-110
Md. Abdul Matin (Department of Materials Science and Engineering, Pukyong National University), Hae-Woong Kwon * (Department of Materials Science and Engineering, Pukyong National University), Jung-Goo Lee (Korea Institute of Materials Science (KIMS)), Ji-Hun Yu (Korea Institute of Materials Science (KIMS))
Abstract

Nd12.5Fe80.6B6.4Ga0.3Nb0.2 HDDR-treated powder was compacted by hot-pressing using different configurations of dies and heating rates. The die configurations were especially different in terms of the evacuation system that was used in heating for hot-pressing. The coercivity in the compacts was influenced by the evacuation system of the die and heating rate. In spite of the identical hot-pressing temperature and heating rate, coercivity was radically reduced above 600 °C in the compacts prepared in the closed-type die compared to that in the compacts prepared in the open-type die. The coercivity in the compacts prepared in the closed-type die decreased with increasing heating rate and the value further increased when extreme high heating rate was employed. Nd12.5Fe80.6B6.4Ga0.3Nb0.2 HDDR-treated powder contained a significant amount of residual hydrogen (approx. 1500 ppm) in the form of Nd2Fe14BHx hydride. The dramatic coercivity decrease in the compact prepared in the closed die is attributed to the disproportionation of Nd2Fe14BHx hydride. High coercivity is mainly due to the effective desorption of hydrogen or the suppression of hydrogen-related disproportionation upon hot-pressing.


 

Keywords: HDDR; hot-pressing; residual hydrogen; disproportionation; coercivity
DOI: http://dx.doi.org/10.4283/JMAG.2014.19.2.106
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